Objective To investigate the risk control of plasticizers in Chinese white wine since the risk assessment results of plasticizers in liquor products in 2014 released by The National Health and Family Planning Commission. Methods According to Method for the Determination of Phthalates Esters in Food (GB 5009.271-2016), plasticizers in the collected spirits samples were detected by gas chromatography-mass spectrometry, with the detection limit of DBP and DEHP were 1mg/kg and 5mg/kg respectively. Results In 2021, 100 samples of Chinese spirits were collected in Guangzhou. For the total PAEs, the detection rate was 42% (42/100) and the exceeding rate was 7% (7/100). For DBP , the detection and exceeding rate was 42% and 7% . For DEHP, the detection and exceeding rate was 18% and 0%. In addition, the exceeding and detection rate showed significant differences in different sampling sites and different production years, with spirits samples in online stores and produced in 2014 were higher. Health risk assessment suggested that even if residents in Guangdong Province consumed the average consumption of Baijiu after 2014, the actual risk were within the tolerance range of humans due to the low levels of DBP and DEHP in Chinese spirits. Conclusion The pollution of PAEs in offline stores in Guangzhou city still exists but not prominent, and the main risk originated from Baijiu produced before 2014 purchased online. It is suggested that local authorities strengthen the supervision of the online shopping link of the vintage Baijiu produced before 2014, and consumers were recommended to purchase from regular channels and pay attention to product packaging information, and reduce the purchase and drinking of Baijiu produced before 2014.