常见食用植物油中特征性脂肪酸的检测及鉴别
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TS227

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功能食品资源优化及评价共性技术研究(2012BAD33B01)


Detection and identification of characteristic fatty acids in common edible vegetable oil
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    摘要:

    目的分析常见市售植物油中特征性脂肪酸构成及含量范围,并探讨在此基础上如何综合利用上述指标对常见植物油进行定性鉴别。方法从6个城市采集9个品种125份样品,每种两个批次。按照GB/T 22223—2008方法测定46种脂肪酸,分析植物油中的特征脂肪酸及其构成。结果菜籽油中的特征脂肪酸为芥酸;花生油中为C20∶0、C24∶0和C22∶0脂肪酸;茶油中的油酸含量高达75.45 g/100 g,是其特征脂肪酸;亚麻籽油的特征脂肪酸为α-亚麻酸;葵花籽油的特征脂肪酸为亚油酸;稻米油中棕榈酸含量范围为15.13~16.37 g/100 g,可以此作为其特征进行鉴别;大豆油中n6/n3比值最接近中国营养学会推荐比值;芝麻油中油酸和亚油酸的总含量及棕榈酸和硬脂酸含量的组成特征比较稳定,可以此作为芝麻油的鉴别依据;玉米油中脂肪酸特征不明显。结论结合单体特征脂肪酸、脂肪酸构成以及n6/n3比值分析可达到常见植物油定性检测的目的。

    Abstract:

    Objective To determine the constitution and content range of characteristic fatty acids in common vegetable oils,and to discuss how to utilize these indicators to identify the quality of vegetable oil.Methods One hundred and twenty five common vegetable oil samples of 9 kinds(two batches for each kind) were collected from six cities.The constituents of 46 fatty acids and characteristic fatty acids of vegetable oils were identified according to GB/T 22223—2008.Results The characteristic fatty acids in rapeseed oil,tea oil,flaxseed oil,sunflower oil and rice oil were erucic acid,oleic acid,α-linolenic acid,linoleic acid and palmitic acid,respectively;the characteristic fatty acids in peanut oil were C20∶0,C24∶0 and C22∶0 fatty acids.The ratio of n6/n3 in soybean oil was the most closed to the value recommended by the Chinese nutrition association.The total content of oleic acid and linoleic acid and the characteristic composition of palmitic acid and stearic acid were relatively stable in sesame oil,which could be used for identification.The characteristic fatty acid in corn oil was not obvious.Conclusion Combination of characteristic fatty acid monomer,fatty acid composition,as well as n6/n3 ratio analysis,the purpose of qualitative detection of common vegetable oils could be achieved.

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陈月晓,马玉霞,陆颖,何梅,杨月欣.常见食用植物油中特征性脂肪酸的检测及鉴别[J].中国食品卫生杂志,2012,24(4):301-305.

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