Determination of four ethylenebis dithiocarbamates in vegetables and fruits by UPLC-MS/MS
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Shandong Research Center of Engineering and Technology for Safety Inspection of Food and Drug, Shandong Institute for Food and Drug Control, Shandong Ji’nan 250101, China

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R155

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    Abstract:

    Objective A method of UPLC-MS/MS for the determination of four ethylenebis dithiocarbamates in vegetables and fruits was established.Methods Samples were extracted with lcysteine hydrochloride and alkaline EDTA-Na2 solutions, derived by methyliodide, prurified by QuEChERS method, and determined by UPLC-MS/MS.Results The limit of detection was 5 μg/kg for fruits and 10 μg/kg for vegetables. A good linear relationship was obtained between the peak area and concentration with the correlation coefficient over 0.998. The recoveries were from 82.3% to 115.1%, and the relative standard deviations were 2.3%-6.9%.Conclusion Ethylenebis dithiocarbamates in many kinds of vegetables and fruits could be successfully determined by the proposed method.

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YANG Hao, GONG Pixue, WANG Jun, WANG Deli, XUE Xia, YU Wenjiang. Determination of four ethylenebis dithiocarbamates in vegetables and fruits by UPLC-MS/MS[J].中国食品卫生杂志,2023,35(1):79-85.

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History
  • Received:December 29,2021
  • Revised:
  • Adopted:
  • Online: March 07,2023
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